Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 22, Issue 16, Pages 3500-3508Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201200264
Keywords
fuel cells; oxygen reduction reactions; non-precious metal catalysts; corrole
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Funding
- National Science Council [NSC 100-2218-E-011-013]
- Academia Sinica
- Ministry of Education (MOE Top University Projects) of Taiwan [100H451401]
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Non-precious metal catalysts of the oxygen reduction reaction are highly favored for use in polymer electrolyte fuel cells (PEFC) because of their relatively low cost. Here, a new carbon-black-supported pyrolyzed Co-corrole (py-Co-corrole/C) catalyst of the oxygen reduction reaction (ORR) in a PEFC cathode is demonstrated to have high catalytic performance. The py-Co-corrole/C at 700 degrees C exhibits optimized ORR activity and participates in a direct four-electron reduction pathway for the reduction of O2 to H2O. The H2-O2 PEFC test of py-Co-corrole/C in the cathode reveals a maximum power density of 275 mW cm-2, which yields a higher performance and a lower Co loading than previous studies of Co-based catalysts for PEFCs. The enhancement of the ORR activity of py-Co-corrole/C is attributable to the four-coordinated Co-corrole structure and the oxidation state of the central cobalt.
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