Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 22, Issue 2, Pages 390-396Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201102146
Keywords
synthetic ion channels; current rectification; polymer membranes; optical gating; photosensitive nanostructures
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Funding
- Beilstein-Institut, Frankfurt/Main, Germany
- Ministry of Science and Innovation of Spain
- Programme of Materials [MAT2009-07747]
- FEDER
- KIT Excellence Initiative [A5.7]
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4-oxo-4-(pyren-4-ylmethoxy) butanoic acid is used as a photolabile protecting group to show the optical gating of nanofluidic devices based on synthetic ion channels. The inner surface of the channels is decorated with monolayers of photolabile hydrophobic molecules that can be removed by irradiation, which leads to the generation of hydrophilic groups. This process can be exploited in the UV-light-triggered permselective transport of ionic species in aqueous solution through the channels. The optical gating of a single conical nanochannel and multichannel polymeric membranes is characterised experimentally and theoretically by means of currentvoltage and selective permeation measurements, respectively. It is anticipated that the integration of nanostructures into multifunctional devices is feasible and can readily find applications in light-induced controlled release, sensing, and information processing.
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