4.8 Article

Facile Physical Route to Highly Crystalline Graphene

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 21, Issue 18, Pages 3496-3501

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201101037

Keywords

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Funding

  1. World Class University (WCU) [2008-000-10029-0]
  2. National Research Foundation of Korea (NRF) [2010-00429]
  3. Ministry of Education, Science and Technology (MEST) of Korea
  4. National Research Foundation of Korea [2010-00429] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A physical route is proposed to obtain highly crystalline graphene sheets with minimal oxygen content similar to the precursor graphite. The functional graphene sheets obtained from graphite oxide by low temperature thermal exfoliation are annealed at high temperature (1900 degrees C) in a vacuum (10(-6) torr). The D band intensity in Raman spectroscopy is reduced significantly, while the G band intensity is recovered, similar to the level of precursor graphite. No appreciable oxygen content is observed from X-ray photoelectron spectroscopy and an electrical conductivity of similar to 56 500 S m(-1) is obtained, comparable to 100 900 S m(-1) of the precursor graphite.

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