4.8 Article

Synthesis of Highly Fluorescent and Soluble 1,2,4-Linking Hyperbranched Poly(arylenevinylene) Featuring Intramolecular Energy Funneling

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 20, Issue 10, Pages 1638-1644

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201000267

Keywords

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Funding

  1. Ministry of Education, Science and Technology of the Korea Government [0417-20090011]
  2. Ministry of Knowledge Economy, Republic of Korea [0417-20080037]
  3. National Research Foundation of Korea [2009-0081571, R31-2008-000-10075-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The synthesis and optical properties of a highly soluble (>200 mg mL(-1)) and highly fluorescent (Phi(F) in film = 0.64) 1,2,4-linking hyperbranched poly(arylenevinylene) (1,2,4-hb-PAV) prepared via Wittig reaction of A(3) (biphenyl-tricarbaldehyde) and B-2 (phosphonium salt) monomers is reported. The molecular weight of 1,2,4-hb-PAV can be precisely controlled by the amount of the base (NaOCH3) used in the polymerization. The absorption and photoluminescence (PL) spectra of 1,2,4-hb-PAV shows distinct red-shifts compared to conventional 1,3,5-linking hyperbranched poly(arylenevinylene) (1,3,5-hb-PAV), attributed to the extended pi-conjugation along ortho- (1,2-) and para- (1,4-) links. The inherent energy gradient from the shorter branches to the longer conjugated stem in 1,2,4-hb-PAV enabled a characteristic energy funneling effect, which is absent in conventional hyperbranched polymer of 1,3,5-hb-PAV.

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