Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 20, Issue 24, Pages 4351-4357Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201001308
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Funding
- Russian Foundation for Basic Research (RFBR) [10-03-00443a, 10-03-01009-a]
- Federal Agency for Science and Innovations (FASI) [02.740.11.0749]
- Russian President Foundation [MK-4305.2009.3]
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The problem of batch-to-batch variation of electronic properties and purity of conjugated polymers used as electron donor and photon harvesting materials in organic solar cells is addressed. A simple method is developed for rapid analysis of electronic quality of polymer-based materials. It is shown that appearance of impurities capable of charge trapping changes electrophysical properties of conjugated polymers. In particular, a clear correlation between the effective relaxation time tau(eff) and relative photovoltaic performance (eta/eta(max)) is revealed for samples of poly(3-hexylthiophene) intentionally polluted with a palladium catalyst. This dependence is also valid for all other investigated samples of conjugated polymers. Therefore, fast impedance measurements at three different frequencies allow one to draw conclusions about the purity of the analyzed polymer sample and even estimate its photovoltaic performance. The developed method might find extensive applications as a simple tool for product quality control in the laboratory and industrial-scale production of conjugated polymers for electronic applications.
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