Journal
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
Volume 18, Issue 5-6, Pages 375-380Publisher
SPRINGER
DOI: 10.1007/s10450-012-9416-0
Keywords
Porous aromatic framework; Gas storage; Microporous materials; Electron-rich frameworks; Polytriphenylamine
Categories
Funding
- State Basic Research Project [2011CB808703]
- NSFC [91022030, 20771041]
- 111 program of Ministry of Education
- Ministry of Science and Technology [2006DFA41190]
- Jilin Science and Technology Department Project [20106021]
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A 2D microporous electron-rich porous aromatic framework JUC-Z2 with high physicochemical stability and large surface area was studied in detail for their low-pressure N-2, Ar, H-2, CO2, CH4 sorption. Its hydrogen, methane, and carbon dioxide storage capacities are 181 cm(3) g(-1) (77 K/760 mmHg), 25 cm(3) g(-1) (273 K/760 mmHg), and 71 cm(3) g(-1) (273 K/760 mmHg), respectively. Gas molecule recognition at 273 K was performed and results show only greenhouse gases such as carbon dioxide and methane could be adsorbed onto JUC-Z2.
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