☆ 4.5 Article

Substituent effects on solvent-free epoxidation catalyzed by dioxomolybdenum(VI) complexes supported by ONO Schiff base ligands

INORGANICA CHIMICA ACTA (2015)

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Journal

INORGANICA CHIMICA ACTA
Volume 431, Issue -, Pages 176-183

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2014.12.022

Keywords

Molybdenum; Tridentate Schiff-base ligands; Epoxidation; Organic solvent-free; Catalysis

Categories

Chemistry, Inorganic & Nuclear

Funding

  1. Centre National de la Recherche Scientifique (CNRS)
  2. Institut Universitaire de France (IUF)
  3. Universidad Nacional Autonoma de Mexico
  4. Universite Paul Sabatier
  5. Institut Universitaire Technologique
  6. China Scholarship Council [201208370239]
  7. CONACYT [318435]

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Molybdenum complexes of type [MoO2L](n) (L = tridentate ONO Schiff base ligands based on the salicylidene-2-aminophenolato structure) have been synthesized and used as catalysts for the solvent-free epoxidation of olefins. The effect of donor (diethylamino) and/or acceptor (nitro) substituents has been studied. (C) 2015 Elsevier B.V. All rights reserved.

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