Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 61, Issue -, Pages 204-206Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2015.10.007
Keywords
Cyrhetrenyl azines; Ferrocenyl azines; Nitrofurane; Crystal structure; NMR; Cyclic voltammetry
Categories
Funding
- FONDECYT-Chile [1150601, 1110669]
- CONICYT
- DEA
Ask authors/readers for more resources
A new series of unsymmetrical cyrhetrenyl and ferrocenyl azines that were monosubstituted [(eta(5)-C5H4)-C(R)=N-N=CH(5-NO2-2-C4H2O)]M {with M=Re(CO)(3) and R=H (1a) or R=Me (1b); M=Fe(eta(3)-C5H5) and R=H (2a) or R=Me (2b)} and disubstituted [Fe{(eta(5)-C5H4)-C(Me)=N-N=CH(5-NO2-2-C4H2O)}(2)] (3a) were prepared by condensation reactions of the corresponding organometallic hydrazone [(eta(5)-C5H4)-C(R)=N-NH2)]M with 5-nitro-2-furaldehyde. The H-1 and C-13{H-1} NMR spectra indicated that these compounds adopted an (E,E)-configuration about the C=N - bond and an s-trans conformation about the N1-N2 bond, and this result was confirmed by X-ray crystallographic analyses of 1a and 2b. The opposite electronic effects of the organometallic fragments correlate with the co-planarity of the [(eta(5)-C5H4)-C(R)=N-N=CH(5-NO2-2-C4H2O)] system, the reduction potential of the nitro group (E-1/2) and the chemical shifts of the iminic carbons. (C) 2015 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available