Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 61, Issue -, Pages 24-26Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2015.08.011
Keywords
Bis(benzimidazole); Catalytic property; Coordination polymer; Manganese(II)
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Funding
- National Natural Science Foundation of China [51474086]
- Natural Science Foundation-Steel and Iron Foundation of Hebei Province [B2015209299]
- Hercules Foundation [AUGE/11/029]
- Research Fund Flanders (FWO)
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An unusual 3D manganese(II) coordination polymer based on the flexible bis(benzimidazole) ligand, namely, [Mn(L)(ndc)](n) (L= 1,4-bis(5,6-dimethylbenzimidazol-1-ylmethyl)benzene, H(2)ndc = 2,6-naphthalenedicarboxylic acid), was synthesized and characterized by IR, elemental analysis, thermal gravimetric and single-crystal X-ray diffraction. The complex exhibits an unprecedented three-fold interpenetrating xah architecture with a (4,5)-connected (4(2).6(2),8(2))(4(6).6(4)) topology, which represents the first binodal (4,5)-connected xah network observed incoordination polymers. The fluorescence and catalytic properties of the complex for the degradation of the Congo red dye in a photo-Fenton-like process were investigated. (C) 2015 Elsevier B.V. All rights reserved.
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