Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 55, Issue -, Pages 123-128Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2015.03.033
Keywords
Metal-organic frameworks; Metalloporphyrin frameworks; Crystal structure; Porous material; Adsorption
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Funding
- National Natural Science Foundation of China [21271148]
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We have achieved success in obtaining three novel two-dimensional porous metalloporphyrin frameworks (MPFs) through solvothermal reactions, by using 5,15-di(4-pyridyl)-10,20-bis(3,4,5-trifluorophenyl) porphyrin (trans-Py-2(F-3-ph)(2)Por) metalated with Fe (1), Co (2), and Ni (3) salts respectively. TGA reveals that they all have high thermal stabilities. Gas adsorption studies indicate that three MPFs have relatively preferable H-2 uptake capacities and the selective adsorption of CO2 over N-2. (C) 2015 Elsevier B.V. All rights reserved.
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