Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 51, Issue -, Pages 46-49Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2014.11.005
Keywords
Tetradentate ligand; Iron(III) complex; Crystal structure; Hydrogen bonding; Antiferromagnetic interaction
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2013007314]
- Institute for Basic Science (IBS) [IBS-R007-D1-2012-a01]
- MEST
- POSTECH
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Dinuclear iron(III) complexes, [(phenO)Fe(SO4)](2)center dot 2CH(3)OH (1) and [(bpmapO)Fe(NO3)](2)(NO3)(2)center dot 3CH(3)OH (2) have been prepared by the reaction of phenOH/bpmapOH and FeSO4 center dot 7H(2)O/Fe(NO3)(3)center dot 9H(2)O in methanol, respectively (phenOH = N-(2-pyridylmethyl)-N'-(2-hydroxyethyl)ethylenediamine, bpmapOH = N-(bis(2-pyridylmethyl)amino)-2-methylpropan-2-ol). Both complexes are ethoxy-bridged dinuclear species and the iron(III) ions in 1 and 2 have distorted octahedral geometries. Both complexes show strong antiferromagnetic interactions through the bridged ethoxy groups within the dimeric units. (C) 2014 Elsevier B.V. All rights reserved.
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