Journal
INORGANIC CHEMISTRY
Volume 54, Issue 19, Pages 9381-9383Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01431
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- FAPERJ
- CNPq (Brazil)
- LDRX-UFF (Brazil)
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Two isostructural ID complexes, [M(hfac)(2)NaphNN](n) [M = Mn-II (1) or Co-II (2); NaphNN = 1-naphthyl nitronylnitroxide], were synthesized and exhibit very strong antiferromagnetic metal radical exchange coupling. Compound 2 shows slow magnetic relaxation behavior with a high blocking temperature (T-B approximate to 13.2 K) and a very high coercive field of 49 kOe at 4.0 K.
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