Journal
INORGANIC CHEMISTRY
Volume 54, Issue 17, Pages 8375-8379Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01045
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Funding
- NSFC [21222102, 21373220, 51402296, 21171166, 21301172]
- 973 Key Program of MOST [2011CB935904]
- NSF for Distinguished Young Scholars of Fujian Province [2014J06015]
- Chunmiao Projects of Haixi Institute of Chinese Academy of Sciences [CMZX-2013-002, CMZX-2015-003]
- Youth Innovation Promotion Association CAS
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Poor stability has long been a major obstacle to the practical applications of metal organic framework (MOF) photocatalysts. This problem can be overcome by the use of structural interpenetration. In this work, by modifying Ru metalloligands, we have rationally designed two Ru-polypyridine based MOFs (with non-interpenetrated and interpenetrated structures, respectively), both of which exhibit similar photocatalytic activities for CO, photoreduction. Remarkably, the interpenetrated Ru-MOF possesses good photocatalytic durability and recyclability, and shows much higher thermal and photic stability in comparison with its non-interpenetrated counterpart. To the best of our knowledge, this is the first time that the stability of MOF photocatalysts was improved by using structural interpenetration.
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