4.7 Article

A Clean and General Strategy To Decorate a Titanium Metal Organic Framework with Noble-Metal Nanoparticles for Versatile Photocatalytic Applications

Journal

INORGANIC CHEMISTRY
Volume 54, Issue 4, Pages 1191-1193

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic502609a

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Funding

  1. National Natural Science Foundation of China [21273036, 21177024]
  2. National Science Foundation [CHE-1213795]
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1213795] Funding Source: National Science Foundation

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We demonstrate a facile and general approach for the fabrication of highly dispersed Au, Pd, and Pt nanoparticles (NPs) on MIL-125(Ti) without using extra reducing and capping agents. Noble-metal NP formation is directed by an in situ redox reaction between the reductive MIL-125(Ti) with Ti3+ and oxidative metal salt precursors. The resulting composites function as efficient photocatalysts.

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