Journal
INORGANIC CHEMISTRY
Volume 54, Issue 7, Pages 3290-3296Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic5029383
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Funding
- Pre-973 Program [2010CB635114]
- National Natural Science Foundation of China [21371099, 21471080]
- Science and Technology Development Planning of Jilin Province [20140203006GX]
- Jiangsu Specially-Appointed Professor
- NSF of Jiangsu Province of China [BK20130043]
- Natural Science Research of Jiangsu Higher Education Institutions of China [13KJB150021]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Foundation of Jiangsu Collaborative Innovation Center of Biomedical Functional Materials
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A stable porous carbazole-based luminescent metalorganic framework, NENU-522, was successfully constructed. It is extremely stable in air and acidic/basic aqueous solutions, which provides the strategy for luminescent material encapsulation of Ln(3+) ions with tunable luminescence for application in light emission. More importantly, Ln(3+)@NENU-522 can emit white light by encapsulating different molar ratios of Eu3+ and Tb3+ ions. Additionally, Tb3+@NENU-522 is found to be useful as a fluorescent indicator for the qualitative and quantitative detection of nitroaromatic explosives with different numbers of -NO2 groups, and the concentrations of complete quenching are about 2000, 1000, and 80 ppm for nitrobenzene, 1,3-dinitrobenzene, and 2,4,6-trinitrophenol, respectively. Meanwhile, Tb3+@NENU-522 displays high selectivity and recyclability in the detection of nitroaromatic explosives.
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