Journal
INORGANIC CHEMISTRY
Volume 54, Issue 4, Pages 1185-1187Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic502478u
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Funding
- Carbon Management Canada
- Alberta Innovates Technology Futures
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Phosphonate monoesters are atypical linkers for metal-organic frameworks, but they offer potentially added versatility. In this work, a bulky isopropyl ester is used to direct the topology of a copper(II) network from a dense to an open framework, CALF-30. CALF-30 shows no adsorption of N-2 or CH4 however, using CO2 sorption, CALF-30 was found to have a Langmuir surface area of over 300 m(2)/g and to be stable to conditions of 90% relative humidity at 353 K owing to kinetic shielding of the framework by the phosphonate ester.
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