Journal
INORGANIC CHEMISTRY
Volume 54, Issue 4, Pages 1206-1208Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic502874n
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Funding
- 973 Program [2013CB933403]
- National Natural Science Foundation of China [91222104, 21171103, 20121318518]
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Two cyano- and phenoxo-bridged hexanuclear (Ni2Dy2Fe2III)-Dy-II-Fe-III (1) and octanuclear (Ni4Dy2Fe2III)-Dy-II-Fe-III (2) trimetallic cyclic complexes have been obtained. They are the first trimetallic metallocycles. Magnetic studies reveal that 1 and 2 exhibit single-molecule-magnet behavior with an energy barrier of 17.9 K for complex 1 in a 2000 Oe static field and 25.0 K for complex 2 in a zero static field.
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