Journal
INORGANIC CHEMISTRY
Volume 54, Issue 8, Pages 3719-3721Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b00185
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Funding
- National Natural Science Foundation of China [20871063, 21271096]
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Herein, two stable lead(II) molecular-bowl-based metalorganic frameworks and their micro- and nanosized forms with open metal sites were presented. These materials could act as Lewis acid catalysts to cyanosilylation reaction. Moreover, the catalytic performances are size-dependent, with the catalyst with nanosized form being 1 order of magnitude more efficient than those with micro- and millisized forms.
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