Journal
INORGANIC CHEMISTRY
Volume 54, Issue 5, Pages 2103-2108Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic5021884
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Funding
- NSF of China [21171013, 51372158, 21471010]
- Ministry of Science and Technology of China [2013CB933402, 2011CB932601]
- Jiangsu Specially Appointed Professor Program [SR10800113]
- Project for Jiangsu Scientific and Technological Innovation Team
- Czech Science Foundation/GACR [P208/10/1724]
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Two Sm@C-82 isomers have been Well Characterized for the first time by means of C-13 NMR Spectroscopy, and their structures were unambiguously determined as Sm@C-2v(9)-C-82 and Sm@C-3v(7)-C-82, respectively. A combined study of single crystal X-ray diffraction and theoretical calculations Suggest that in Sm@C-2v(9)-C-82 the preferred Sm2+ ion position shall be located in a region slightly off the C-2 axis of C-2v(9)-C-82. Moreover, the electrochemical surveys on these Sm@C-82 isomers reveal that their redox activities are mainly determined by the properties of their carbon cages.
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