4.7 Article

A Naphthalenediimide-Based Metal-Organic Framework and Thin Film Exhibiting Photochromic and Electrochromic Properties

Journal

INORGANIC CHEMISTRY
Volume 55, Issue 2, Pages 549-551

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b02480

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Funding

  1. National Natural Science Foundation of China [91122012, 21471086]
  2. Social Development Foundation of Ningbo [2014C50013]
  3. K.C. Wong MagnaFund in Ningbo University

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A multifunctional metalorganic framework, NBU-3, has been explored as a 2D three-connected network based on a naphthalenediimide-based ligand. The NBU-3 crystals display photochromic properties, and NBU-3 thin films on FTO substrates exhibit electrochromic properties. NBU-3 is the first example of MOF materials containing both photochromic and electrochromic properties, which can be desirable for thin film devices.

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