4.7 Article

Gas Sorption, Second-Order Nonlinear Optics, and Luminescence Properties of a Multifunctional srs-Type Metal-Organic Framework Built by Tris(4-carboxylphenylduryl)amine

Journal

INORGANIC CHEMISTRY
Volume 54, Issue 13, Pages 6653-6656

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01023

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Funding

  1. Chinese Academy of Sciences [XDA07070200]
  2. National Science Foundation of China [21403235, 21425102, 21221001, 91222105]
  3. 973 program [2012CB821705]

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A chiral 8-fold interpenetrating srs-type metal-organic framework FIR-28 (FIR denotes Fujian Institute of Research) exhibits a surface area of 1029 m(2)/g and high C3H8/CH4 separation capacity in excess of 154 and displays strong powder second-harmonic-generation efficiency, with more than half over potassium dihydrogen phosphate powder. Moreover, the luminescence properties of FIR-28 are dependent on the solvent guests.

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