Journal
INORGANIC CHEMISTRY
Volume 54, Issue 24, Pages 11587-11589Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b02037
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Funding
- NSF of China [21203022, 21261001, 21361001]
- Natural Science Foundation of Jiangxi Province of China [20143ACB20002, 20151BAB203001]
- Young Scientist Training Program of Jiangxi Province of China [20142BCB23018]
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Herein, we report a robust azo-metal-organic framework (MOF), namely, ECUT-15, which can be described as a 10-connected bct net built on trinudear Co-3 subunits. The activated samples of it perform a somewhat breathing behavior. Most importantly, under UV irradiation, this MOP performs outstanding photoswitching behavior toward CO2, giving great variation in the CO2 capture/release performance, for example, 45% under static conditions and 75% under dynamic measurements, as well as instantaneous release of up to 78%.
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