Journal
INORGANIC CHEMISTRY
Volume 54, Issue 7, Pages 3107-3117Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic502930p
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Funding
- DFG Center for Functional Nanostructures
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Reactions of the N-substituted diethanolamine ligand N-n-butyldiethanolamine with chromium(II) and lanthanide(III)/rare earth salts (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) in the presence of coligands give access to three series of isostructural 1:1 3d(Cr-III)/4f(Ln(III)) coordination cluster compounds that can be designated in terms of octanuclear square-in-square (Ln = La-Tb), hexanuclear triangle-in-triangle (Ln = Dy, Ho, Y) and tetranuclear butterfly or defect dicubane core (Ln = Er-Lu) topologies as revealed by single-crystal X-ray crystallographic analysis. The bulk magnetic properties were also measured. The influences of the various components in the reaction system on the final topology and the role of the ionic radius are discussed.
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