Microstructure and mechanical properties of constrained shape-memory alloy nanograins and nanowires

We use the phase-field method to study the martensitic transformation at the nanoscale. For nanosystems such as nanowires and nanograins embedded in a stiff matrix, the geometric constraints and boundary conditions have an impact on martensite formation, leading to new microstructures - such as dots aligned on a square lattice with axes along < 0 1 > - or preventing martensite formation altogether. We also perform tension tests on the nanowires. The stress-strain curves are very different from bulk results. Moreover, they are weakly affected by microstructures - the mechanical response of nanowires with different microstructures may be similar, while nanowires with the same microstructure may have a different mechanical behavior. We also observe that at the transition temperature, or slightly below it, the narrowest wires behave pseudoelastically whereas wider wires are in the memory-shape regime. Moreover, the yield stress does not change monotonically with width: it has a minimum value at intermediate width. (c) 2008 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.