Journal
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume 68, Issue -, Pages M1476-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536812045801
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- Russian Fund for Basic Research [12-03-00076]
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In the title compound, [PdCl2(C15H11NO3)(2)]center dot CHCl3, the Pd-II atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyanophenyl ligands. The molecular conformation is stabilized by pi-pi stacking interactions [shortest centroid-centroid distance = 3.600 (1) angstrom] between substituted benzene rings of different ligands. The crystal packing is characterized by C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions involving the chloroform solvent molecules.
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