Journal
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume 68, Issue -, Pages M1468-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536812045126
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Funding
- UK Engineering and Physical Sciences Research Council [EP/F063733/1]
- Career Acceleration Fellowship [EP/J001872/1]
- Royal Society for a Wolfson research merit award
- Royal Society of Edinburgh/BP Trust
- University of Strathclyde RDF award
- EPSRC [EP/J001872/1, EP/F063733/1] Funding Source: UKRI
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The title compound, [Na-2(C6H18NSi2)(2)(C6H16N2)] n, was found to consist of dimeric [Na(NSiMe3)(2)] units with crystallographically imposed centrosymmetry based upon fourmembered NaNNaN rings. The dimers are bridged by N, N, N', N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.
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