Journal
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume 65, Issue -, Pages M1262-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536809038331
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- Natural Science Foundation of Guangdong Province [0430064)]
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The title coordination polymer, [Cu(C6H3BrNO2)(2)](n), is composed of two structurally similar two-dimensional coordination polymers (twin layers). Both of them have the same chemical composition but they display different bond lengths and angles. In each layer, two N atoms and four carboxylate O atoms from the bridging 5-bromonicotinate ligands and four carboxylate O atoms from the terminal 5-bromonicotinate ligands bind to two Cu-II atoms to form a dinuclear paddle-wheel-like pattern. Adjacent paddle wheels are further linked by bridging 5-bromonicotinate groups to generate a two-dimensional coordination polymer; neighboring twin-like layers are finally stacked through van der Waals interactions in a 'sandwich' manner, thus generating a three-dimensional supramolecular structure.
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