Journal
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volume 67, Issue -, Pages O417-O420Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108270111035165
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Funding
- American Chemical Society [PRF 44692.01-GB]
- Research Corporation [CC6755]
- ANPCyT [PME-2006-01113]
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The title compound, C9H14N+center dot CHB11Cl11-, was obtained in the course of our continuing studies of the low-melting salts of closo-and nido-carborane cage anions with alkylpyridinium and dialkylimidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butylpyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds.
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