Journal
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volume 65, Issue -, Pages M299-M301Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108270109017831
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- Robert A. Welch Foundation, Houston, Texas
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The title compound, [Au(C7H7S)(C18H15P)], is conformationally chiral and crystallizes from benzene - hexane as individually enantiopure crystals. This mononuclear compound has the Au I atom linearly bound to a triphenylphosphine P atom and to a phenyl C atom of a 2-(methylsulfanyl) phenyl group. The angle at the Au I atom is 175.9 (2)degrees. The linear ligand coordination about the Au I atom has geometric parameters inside the remarkably narrow range found for gold complexes bound by a phosphine ligand and by the ortho-C atom of a substituted phenyl group. This is the first example of gold(I) attached to a methylsulfanyl aromatic carbanion.
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