Journal
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volume 65, Issue -, Pages M198-M200Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108270109013110
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- Swedish International Development Agency
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The title compound, [Ag(C3H6N6)(2)]NO3, has an alternating two-dimensional bilayer structure supported by extensive hydrogen bonds. The [Ag(melamine)(2)](+) cationic monomers (melamine is 1,3,5-triazine-2,4,6-triamine) are connected via N-H center dot center dot center dot N hydrogen bonds to form two-dimensional sheets. Nitrate groups are sandwiched between two sheets through N-H center dot center dot center dot O hydrogen bonds. An almost perfectly linear coordination geometry is found for the Ag I ions. The triazine ligands are slightly distorted due to pi-pi interactions.
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