Journal
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
Volume 68, Issue -, Pages 549-557Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108768112033484
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A complex, disorder-free structure in the space group P1 has been established for l-tryptophan, for which no crystal structure has previously been available. The 16 molecules in the asymmetric unit can be divided into two groups of eight; one where the side chains have gauche orientations and one with trans orientations. Molecules within each group have almost identical molecular geometries. The unit-cell parameters mimic a hexagonal cell, but deviations from 90 degrees for the cell angles alpha = 84.421 (4) and beta = 87.694 (4)degrees give a small tilt that rules out hexagonal symmetry. The hydrogen-bonding pattern resembles that found in the crystal structure of the racemic structure of DL-tryptophan, but a lower density combined with longer hydrogen bonds and inter-aromatic interactions show that the enantiomeric structure is less efficiently packed.
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