Journal
ACTA CHIMICA SINICA
Volume 70, Issue 16, Pages 1679-1681Publisher
SCIENCE PRESS
DOI: 10.6023/A12040135
Keywords
transition metal; catalysis; trifluoromethylation; C-H activation; directing; cross-coupling
Categories
Funding
- 973 Project from the Ministry of Science and Technology of the People's Republic of China [2009CB825300]
- National Natural Science Foundation of China [20925207, 21002001]
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In recent years, transition metal-catalyzed C-H trifluoromethylation has been well developed, which is mainly focused on the terminal alkyne C(sp)-H, aromatic and heterocyclic C(sp(2))-H and allylic C(sp(3))-H trifluoromethylation. This paper briefly overviews the latest developments in this field, the characteristics of various types of reaction, as well as the facing challenges and future direction.
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