Journal
ACS NANO
Volume 8, Issue 2, Pages 1463-1467Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn405469g
Keywords
thin films; metal-organic frameworks; photoswitching; molecular release; azobenzene
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The remote control of surface properties is one of the key challenges in interfacial systems chemistry. Here, we report the realization of a SURMOF (surface-mounted metal-organic framework)-based hybrid system in which a crucial component can be switched by light. The realization of this two-component system is made possible by installing vertical compositional gradients via liquid-phase epitaxy. After loading the porous coating with guest molecules, its release is initiated by illumination with visible light and monitored by a quartz crystal microbalance.
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