4.8 Article

Poly(vinyl alcohol) Reinforced and Toughened with Poly(dopamine)-Treated Graphene Oxide, and Its Use for Humidity Sensing

Journal

ACS NANO
Volume 8, Issue 7, Pages 6739-6747

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nn500504s

Keywords

graphene oxide; poly(dopamine); nanocomposite; interfacial adhesion; reinforcement; toughening; humidity sensing

Funding

  1. Center for Advanced Soft Electronics under the Global Frontier Research Program through the National Research Foundation (NRF) - Ministry of Science, ICT and Future Planning (MSIE), Korea
  2. Ministry of Education (MOE)
  3. NRF through the BK21 Plus Program (META-material-based Energy Harvest and Storage Technologies) [10Z20130011057]
  4. Human Resource Training Project for Regional Innovation [2012H1B8A2026133]

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Poly(dopamine)-treated graphene oxide/poly(vinyl alcohol) (dG-0/PVA) composite films were made and characterized. G-0 was modified with poly(dopamine) in aqueous solution and then chemically reduced to yield poly(dopamine)-treated reduced G-0. A combination of hydrogen bonding, strong adhesion of poly(dopamine) at the interface of PVA and G-0 sheets, and reinforcement by G-0 resulted in increases in tensile modulus, ultimate tensile strength, and strain-to-failure by 39, 100, and 89%, respectively, at 0.5 wt % dG-0 loading of the PVA. The dG-0 serves as a moisture barrier for water-soluble PVA, and the dG-0/PVA composite films were shown to be effective humidity sensors over the relative humidity range 40-100%.

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