4.8 Article

A Strong Integrated Strength and Toughness Artificial Nacre Based on Dopamine Cross-Linked Graphene Oxide

Journal

ACS NANO
Volume 8, Issue 9, Pages 9511-9517

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nn503755c

Keywords

artificial nacre; graphene oxide; bioinspired; integrated high performance; mechanical properties

Funding

  1. National Research Fund for Fundamental Key Projects [2010CB934700]
  2. National Natural Science Foundation of China [21273017, 51103004, 91127038]
  3. Program for New Century Excellent Talents in University [NCET-12-0034]
  4. Beijing Nova Program [Z121103002512020, Z131103000413051]
  5. Beijing Science and Technology Program [Z121100001312004]
  6. Fok Ying-Tong Education Foundation [141045]
  7. Open Project of Beijing National Laboratory for Molecular Sciences
  8. 111 Project [B14009]
  9. Fundamental Research Funds for the Central Universities [YWF-14-HXXY-018]

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Demands of the strong integrated materials have substantially increased across various industries. Inspired by the relationship of excellent integration of mechanical properties and hierarchical nano/microscale structure of the natural nacre, we have developed a strategy for fabricating the strong integrated artificial nacre based on graphene oxide (GO) sheets by dopamine cross-linking via evaporation-induced assembly process. The tensile strength and toughness simultaneously show 1.5 and 2 times higher than that of natural nacre. Meanwhile, the artificial nacre shows high electrical conductivity. This type of strong integrated artificial nacre has great potential applications in aerospace, flexible supercapacitor electrodes, artificial muscle, and tissue engineering.

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