Journal
ACS NANO
Volume 7, Issue 5, Pages 4610-4616Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn401420h
Keywords
two-dimensional material; alloy; transition-metal dichalcogenide; band gap; photoluminescencedensity; functional theory calculation
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Funding
- China 973 program [2011CB932803]
- National Natural Science Foundation of China [21273124, 21290191]
- National Science Council of Taiwan under Project Nos [NSC 100-2112-M-011-001-MY3, NSC 101-2811-M-011-002]
- JST research acceleration program
- Grants-in-Aid for Scientific Research [25107003] Funding Source: KAKEN
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Band gap engineering of atomically thin two-dimensional (2D) materials is the key to their applications in nanoelectronics, optoelectronlcs, and photonics. Here, for the first time, we demonstrate that in the 2D system, by alloying two materials with different band gaps (MoS2 and WS2), tunable band gap can be obtained in the 2D alloys (Mo1-xWxS2 monolayers, x = 0-1). Atomic-resolution scanning transmission electron microscopy has revealed random arrangement of Mo and W atoms In the Mo1-xWxS2 monolayer alloys. Photoluminescence characterization has shown tunable band gap emission continuously tuned from 1.82 eV (reached at x = 0.20) to 1.99 eV (reached at x= 1). Further, density functional theory calculations have been carried out to understand the composition-dependent electronic structures of Mo1-xWxS2 monolayer alloys.
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