Journal
ACS NANO
Volume 6, Issue 2, Pages 1532-1540Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn204491q
Keywords
polymer adsorption; biomimetic membranes; self-assembly; block copolymers; micelles; surfactants
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Funding
- U.S. Department of Energy [DE-AC52-06NA25396]
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The deposition of amphiphilic poly(ethylene oxide)-block-poly(butadiene) (PEO-b-PBD) copolymer micelles is demonstrated on solid substrates. Depending upon surface chemistry, micelle adsorption creates either monolayer or bilayer films. Lateral diffusion measurements reveal that strong coupling between hydrophilic surfaces and PEO blocks creates immobile bilayers, while monolayers retain the fluidity previously observed in vesicular assemblies.
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