4.8 Article

Ferromagnetic Germanide in Ge Nanowire Transistors for Spintronics Application

Journal

ACS NANO
Volume 6, Issue 6, Pages 5710-5717

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nn301956m

Keywords

germanium nanowire heterostructure; Mn5Ge3; manganese germanide; atomically clean interface; spin injection

Funding

  1. Western Institution of Nanoelectronics (WIN)
  2. Focus Center on Functional Engineered Nano Architectonics (FENA)
  3. National Science Council [NSC 98-2221-E-007-104-MY3, NSC 100-2628-E-007-029-MY2]
  4. National Tsing Hua University [100N2060E1, 100N2041E1]

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To explore spintronics applications for Ge nanowire heterostructures formed by thermal annealing, it is critical to develop a ferromagnetic germanide with high Curie temperature and take advantage of the high-quality interface between Ge and the formed ferromagnetic germanide. In this work, we report, for the first time, the formation and characterization of Mn5Ge3/Ge/Mn5Ge3 nanowire transistors, in which the room-temperature ferromagnetic germanide was found through the solid-state reaction between a single-crystalline Ge nanowire and Mn contact pads upon thermal annealing. The atomically clean interface between Mn5Ge3 and Ge with a relatively small lattice mismatch of 10.6% indicates that Mn5Ge3 is a high-quality ferromagnetic contact to Ge. Temperature-dependent I-V measurements on the Mn5Ge3/Ge/Mn5Ge3 nanowire heterostructure reveal a Schottky barrier height of 0.25 eV for the Mn5Ge3 contact to p-type Ge. The Ge nanowire field-effect transistors built on the Mn5Ge3/Ge/Mn5Ge3 heterostructure exhibit a high-performance p-type behavior with a current on/off ratio close to 10(5), and a hole mobility of 150-200 cm(2)/(V s). Temperature-dependent resistance of a fully germanided Mn5Ge3 nanowire shows a clear transition behavior near the Curie temperature of Mn5Ge3 at about 300 K. Our findings of the high-quality room-temperature ferromagnetic Mn5Ge3 contact represent a promising step toward electrical spin injection into Ge nanowires and thus the realization of high-efficiency spintronic devices for room-temperature applications.

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