4.8 Article

Nonlinear Photoluminescence Imaging of Isotropic and Liquid Crystalline Dispersions of Graphene Oxide

Journal

ACS NANO
Volume 6, Issue 9, Pages 8060-8066

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nn302644r

Keywords

graphene oxide; self-assembly; liquid crystals; multiphoton excitation; photoluminescence; nonlinear imaging

Funding

  1. NSF [DMR-0645461, DMR-0820579, DMR-0847782]
  2. AFOSR [FA9550-09-1-0590, FA9550-09-1-0581]
  3. Welch Foundation [C-1668]
  4. ICAM Branches Cost Sharing Fund
  5. AFRL through University Technology Corporation [09-S568-064-01-C1]
  6. Office of Naval Research Graphene MURI Program [00006766, N00014-09-1-1066]
  7. Direct For Mathematical & Physical Scien [844115] Funding Source: National Science Foundation
  8. Division Of Materials Research [844115] Funding Source: National Science Foundation
  9. Division Of Materials Research
  10. Direct For Mathematical & Physical Scien [0847782] Funding Source: National Science Foundation

Ask authors/readers for more resources

We report a visible-range nonlinear photoluminescence (PL) from graphene oxide (GO) flakes excited by near-infrared femtosecond laser light. PL intensity has nonlinear dependence on the laser power, implying a multiphoton excitation process, and also strongly depends on a linear polarization orientation of excitation light, being at maximum when it is parallel to flakes. We show that PL can be used for a fully three-dimensional label-free imaging of isotropic, nematic, and lamellar liquid crystalline dispersions of GO flakes in water. This nonlinear PL is of interest for applications in direct label-free imaging of composite materials and study of orientational ordering in mesomorphic phases formed by these flakes, as well as in biomedical and sensing applications utilizing GO.

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