Journal
ACS NANO
Volume 6, Issue 5, Pages 3841-3852Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn204960c
Keywords
electrochemical; dynamic strain; microscopy; charge writing
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Funding
- U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division
- National Science Foundation (NSF) [DMR-0906443]
- EPSRC
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0906443] Funding Source: National Science Foundation
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Local electrochemical phenomena on the surfaces of the LaAlO3-SrTiO3 heterostructure are explored using unipolar and bipolar dynamic electrochemical strain microscopy (D-ESM). The D-ESM suggests the presence of at least two distinct electrochemical processes, Including fast reversible low-voltage process and slow high-voltage process. The latter process Is associated with static surface deformations In the sub-nanometer regime. These behaviors are compared with Kelvin probe force microscopy hysteresis data. The possible origins of observed phenomena are discussed, and these studies suggest that charge-writing behavior in LAO-STO includes a strong surface/bulk electrochemical component and is more complicated than simple screening by surface adsorbates.
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