Journal
ACS NANO
Volume 5, Issue 7, Pages 6039-6051Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn2018683
Keywords
ultralarge graphene oxide; Langmuir-Blodgett assembly; transparent conductive films; graphene oxide wrinkles; self-assembly
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Funding
- Henkel International [ICIPLC001.07/08]
- Hong Kong Research Grant Council [614010]
- School of Engineering at HKUST
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Monolayer graphene oxide (GO) sheets with sizes ranging from a few to similar to 200 mu m are synthesized based on a chemical method and are sorted out to obtain four different grades having uniform sizes. Transparent conductive films are produced using the ultralarge graphene oxide (UL-GO) sheets that are deposited layer-by-layer on a substrate using the Langmuir-Blodgett (LB) assembly technique. The density and degree of wrinkling of the UL-GO monolayers are turned from dilute, dose-packed flat UL-GO to graphene oxide wrinkles (GOWs) and concentrated graphene oxide wrinkles (CGOWs) by varying the LB processing conditions. The method demonstrated here opens up a new avenue for high-yield fabrication of GOWs or CGOWs that are considered promising materials for hydrogen storage, supercapacitors, and nanomechanical devices. The films produced from UL-GO sheets with a dose-packed flat structure exhibit exceptionally high electrical conductivity and transparency after thermal reduction and chemical doping treatments. A remarkable sheet resistance of similar to 500 Omega/sq at 90% transparency is obtained, which outperforms the graphene films grown on a NI substrate by chemical vapor deposition. The technique used in this work to produce transparent conductive UL-GO thin films is facile, inexpensive, and tunable for mass production.
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