Journal
ACS NANO
Volume 3, Issue 6, Pages 1365-1372Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn900099t
Keywords
porous nanorods; hollow nanostructures; electrodeposition; galvanic replacement; template directed synthesis; polycrystalline silver nanorods; surface plasmon resonance
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Funding
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canada Research Chairs Program, and Simon Fraser University (Trust Endowment Fund)
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An important aspect of synthesizing designer nanostructures is fine-tuning their size, composition, and surface area. These parameters often dictate the unique properties of nanoparticles relative to their bulk counterpart. This paper reports the synthesis of porous metal nanorods with well-controlled dimensions, porosity, and photonic properties. The growth of each nanostructure is directed by a polycrystalline sacrificial template of silver with well-defined, tunable dimensions. This template can be selectively etched to isolate a porous hollow nanostructure. The porosity, composition, and photonic characteristics of this nanostructure are adjustable by controlling the reaction conditions.
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