Journal
ACS NANO
Volume 3, Issue 12, Pages 4098-4104Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nn9009278
Keywords
graphene; carbon nanofibers; carbon nanotubes; carbothermal reduction; nonmetal catalysis; SiC
Categories
Funding
- European Network CARBIO [MRTN-CT-2006-035616]
- Cusanuswerk
- EU
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The use of SiO2 as a catalyst for graphitic nanostructures, such as carbon nanotubes and graphene, is a new and rapidly developing catalyst system. A key question is whether carbide phases form in the reaction. We show the formation of SiC from SiO2 nanoparticles for the synthesis of graphitic carbon nanostructures via chemical vapor deposition (CVD) at 900 degrees C. Our findings point to the carbothermal reduction of SiO2 in the CVD reaction. The inclusion of triethyl borate apparently accelerates the process and leads to improved yields. The study helps better understand the growth mechanisms at play in carbon nanotube and carbon nanofiber formation when using SiO2 catalysts.
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