4.8 Article

Sunlike White-Light-Emitting Diodes Based on Zero-Dimensional Organic Metal Halide Hybrids

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 36, Pages 30051-30057

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b12474

Keywords

white LED; organic metal halide hybrid; down conversion phosphor; high color rendering index; solid-state lighting

Funding

  1. National Science Foundation (NSF) [DMR-1709116]
  2. Air Force Office of Scientific Research (AFOSR) [17RT0906]

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Here we report ultraviolet (UV)-pumped white-light-emitting diodes (WLEDs) with sunlike full spectrum emissions, by using a commercially available blue phosphor (BaMgAl10O17:Eu2+) and a series of broadband zero-dimensional (OD) organic metal halide hybrids as down conversion phosphors. By controlling the blend ratio of phosphors, we have achieved high-quality WLEDs with excellent general color rendering index (CRI R-a) of up to 99 and deep-red rendering index (R9) of up to 99. These WLEDs exhibiting white emissions with correlated color temperatures (CCTs) ranging from 3000 to 6000 K perfectly mimic sunlight at different times of day.

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