Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 35, Pages 29417-29424Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b07437
Keywords
supramolecular organic photocatalysts; water cluster; donor-acceptor stacks; hydrogen evolution; dye degradation
Funding
- DST (SERB), New Delhi, India
- IIT KGP
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Supramolecular organic photocatalysts are scarcely explored for the generation of sustainable energy as well as for environmental remediation purposes. An organic photocatalyst, containing a cubanelike water cluster and donor acceptor stacks, was efficiently developed through a supramolecular approach. The material exhibited remarkable photocatalytic hydrogen generation, in the absence of any cocatalyst, with excellent stability and recyclability. The photoactivity was further assessed through time-resolved photoluminescence and electrochemical impedance spectroscopy. The material also exhibited highly efficient sunlight-driven photocatalytic activity through the degradation of harmful organic dye methylene blue.
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