4.8 Article

ITO/Au/ITO Sandwich Structure for Near-Infrared Plasmonics

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 18, Pages 15743-15752

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am5026165

Keywords

transparent conductive oxide; ITO/Au/ITO; pulsed laser deposition; electrical and optical properties; plasma frequency

Funding

  1. National Basic Research Program of China (973 Program) [2013CB632104]
  2. Natural Science Foundation of Zhejiang Province of China [LZ12F04002]
  3. Research Foundation of State Key Laboratory of Modern Optical Instrumentation
  4. Hong Kong Polytechnic University [A-PL21/A-PM51]

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ITO/Au/ITO trilayers with varying gold spacer layer thicknesses were deposited on glass substrates by pulsed laser deposition. Transmission electron microscopy measurements demonstrated the continuous nature of the Au layer down to 2.4 nm. XRD patterns clearly showed an enhanced crystallinity of the ITO films promoted by the insertion of the gold layer. Compared with a single layer of ITO with a carrier concentration of 7.12 x 10(20) cm(-3), the ITO/Au/ITO structure achieved an effective carrier concentration as high as 3.26 x 10(22) cm(-3). Transmittance and ellipsometry measurements showed that the optical properties of ITO/Au/ITO films were greatly influenced by the thickness of the inserted gold layer. The cross-point wavelength of the trilayer samples was reduced with increasing gold layer thickness. Importantly, the trilayer structure exhibited a reduced loss (compared with plain Au) in the near-infrared region, suggesting its potential for plasmonic applications in the near-infrared range.

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