4.8 Article

Enhanced Cycling Stability of Lithium Sulfur Batteries Using Sulfur Polyaniline-Graphene Nanoribbon Composite Cathodes

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 17, Pages 15033-15039

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am5030116

Keywords

lithium sulfur battery; polyaniline; graphene nanoribbons; sulfur; energy storage

Funding

  1. ONR MURI program [00006766, N00014-09-1-1066]
  2. AFOSR MURI program [FA9550-12-1-0035]
  3. AFOSR [FA9550-09-1-0581]
  4. Chinese Scholarship Council

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A hierarchical nanocomposite material of graphene nanoribbons combined with polyaniline and sulfur using an inexpensive, simple method has been developed. The resulting composite, characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron microscopy, and X-ray diffraction analysis, has a good rate performance and excellent cycling stability. The synergistic combination of electrically conductive graphene nanoribbons, polyaniline, and sulfur produces a composite with high performance. The method developed here is practical for the large-scale development of cathode materials for lithium sulfur batteries.

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