Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 15, Pages 11864-11868Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am503931j
Keywords
poly[2-(dimethylamino)ethyl methacrylate]; polymer brush; ARGET-ATRP; superoleophobic; pH-responsive; large scale
Funding
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan [24120005]
- Grants-in-Aid for Scientific Research [24120005] Funding Source: KAKEN
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Contrary to conventional ATRP, aqueous A(R)GET-ATRP at ambient temperature without deoxygenating reaction solutions is an extremely facile method to create polymer brushes. Using these techniques, extremely thick poly[2-(dimethylamino)ethyl methacrylate] polymer brushes can be prepared (similar to 700 nm), or reaction solutions can be low chemical-content, consisting of 99% v/v water. Based on these techniques, we have also developed an easy and inexpensive method, referred to as paint on-ATRP, that directly pastes reaction solutions onto various large-scale real-life substrates open to the air. The resulting brush surfaces possess excellent oil-repellent properties, which can be activated or deactivated in response to solution pH.
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