4.8 Article

Investigation of a Branchlike MoO3/Polypyrrole Hybrid with Enhanced Electrochemical Performance Used as an Electrode in Supercapacitors

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 2, Pages 1125-1130

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am404724u

Keywords

molybdenum trioxide; polypyrrole; hybrid; energy storage; supercapacitor

Funding

  1. Chinese Academy of Sciences and Technology Project [XBLZ-2011-013]
  2. Technologies R&D Program of Gansu Province [1104FKCA156]

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A branchlike MoO3/polypyrrole conductive nanocomposite was facilely prepared by wrapping a homogeneous polypyrrole (PPy) layer around MoO3 nanobelts via the in situ oxidative polymerization of a self-assembled pyrrole monomer. X-ray powder diffraction characterization demonstrated that the PPy polymer does not hinder the crystallization of the MoO3 nanobelts substrate. The electrochemical tests show, that the specific capacitance of 129 F g(-1) for the MoO3/ PPy hybrid is higher than both pristine MoO3 and pure PPy. Moreover, the hybrid electrode with good electrical conductivity displays good cyclic stability of 90% retention after 200 cycles of charge/discharge. These results indicate a promising potential application of the MoO3/PPy nanocomposite for use as an effective electrode material in supercapacitors.

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