Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 13, Pages 10153-10161Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am501371b
Keywords
PDMS coating; washable and wear-resistant; alkali treatment; self-cleaning properly
Funding
- National Natural Science Foundation of China [51372146]
- Program for New Century Excellent Talents in University [NCET-12-1042]
- Research Fund for the Doctoral Program of Higher Education of China [20116125110002, 20136125110003]
- Major Program of Science Foundation of Shaanxi Province [2011ZKC05-7]
- Key Scientific Research Group of Shaanxi Province [2013KCT-08]
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Superhydrophobic poly(ethylene terephthalate) (PET) textile surfaces with a self-cleaning property were fabricated by treating the microscale fibers with alkali followed by coating with polydimethylsiloxane (PDMS). Scanning electron microscopy analysis showed that alkali treatment etched the PET and resulted in nanoscale pits on the fiber surfaces, making the textiles have hierarchical structures. Coating of PDMS on the etched fibers affected little the roughening structures while lowered the surface energy of the fibers, thus making the textiles show slippery superhydrophobicity with a self-cleaning effect. Wettability tests showed that the superhydrophobic textiles were robust to acid/alkaline etching, UV irradiation, and long-time laundering. Importantly, the textiles maintained superhydrophobicity even when the textiles are ruptured by severe abrasion. Also colorful images could be imparted to the superhydrophobic textiles by a conventional transfer printing without affecting the superhydrophobicity.
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